Let $x\in\left[0,\frac{\pi}{2}\right)\cup\left[\pi,\frac{3\pi}{2}\right)$.
Thus, we need to solve $$\frac{\sin^2x}{\cos{x}}\leq\frac{3}{2}$$ or
$$\frac{(2+\cos x)(2\cos x-1)}{\cos x}\geq0,$$
which is $\cos x\geq\frac{1}{2}$ or $\cos x<0$, which gives $\left[0,\frac{\pi}{3}\right]\cup\left[\pi,\frac{3\pi}{2}\right)$.
Let $x\in\left(\frac{\pi}{2},\pi\right]\cup\left(\frac{3\pi}{2},2\pi\right]$.
Thus, we need to solve $$-\frac{\sin^2x}{\cos{x}}\leq\frac{3}{2}$$ or
$$\frac{(2-\cos x)(2\cos x+1)}{\cos x}\geq0,$$
which is $\cos x\leq-\frac{1}{2}$ or $\cos x>0$, which gives $\left[\frac{2\pi}{3},\pi\right]\cup\left(\frac{3\pi}{2},2\pi\right]$.