Other answers have given you some excellent general procedures for finding the basis for the orthogonal complement of a space. Here’s another one that’s quite simple to apply and doesn’t require a tedious Gram-Schmidt calculation.
Every vector in $W$ is orthogonal to every vector in $W^\perp$, so in particular it’s orthogonal to the vectors in the given spanning set of $W^\perp$. This gives you a system of linear equations that must be satisfied by elements of $W$: $$\begin{align}x_1-x_2&=0\\x_2-x_3&=0\\x_3-x_4&=0.\end{align}$$ So, you can find a basis for $W$ by finding the nullspace of the matrix $$\begin{bmatrix}1&-1&0&0\\0&1&-1&0\\0&0&1&-1\end{bmatrix}.$$ In this particular case, you can quickly find that the nullspace is spanned by $\begin{bmatrix}1&1&1&1\end{bmatrix}^T$.
This technique is generally applicable. To find a basis for the orthogonal complement of the span of a set of vectors, compute the kernel of the matrix that has those vectors as rows, which amounts to solving a homogeneous system of linear equations that capture the orthogonality conditions.
This reflects the fact that there are two basic ways to specify a subspace: you can list a spanning set for it, or you can list a set of dual vectors that annihilate the subspace. It’s also connected to the fact that for a linear map $L$, $\ker(L^*)$ annihilates $\operatorname{im}(L)$ and $\operatorname{im}(L^*)$ annihilates $\ker(L)$.
However, for multiple-choice questions like this one, you can often find the solution even more quickly by inspection. You know that $\mathbb R^4=W\oplus W^\perp$, so you can immediately eliminate the first choice because it has the wrong dimension (it’s easy to verify by inspection that the given spanning set for $W^\perp$ is linearly independent). Since the dot product of any vector in $W$ with one in $W^\perp$ is zero, you know from examining the first vector in $W^\perp$ that the first two coordinates of every vector in $W$ must be equal. This eliminates the second choice and you can then easily verify that the remaining choice is in fact orthogonal to the given generators of $W^\perp$.