First of all: I'll indicate with $\binom n k$ the number of possibilities of taking $n$ sweeties in groups of $k$ sweeties.
Now, we know that the total number of possibilities is $\binom 6 4 = 15$.
The number of possibilities that 2 red sweeties are taken is $\binom 4 2 * \binom 2 2 = 6$.
So, the probability is $\frac 6 {15} = \frac 2 5 = 0.4$.
We can verify the result taking away, from the total number of possibilities, the number of possibilities that $0$ or $1$ red sweeties are taken, and they are $$\binom 4 4 = 1 $$
$$\binom 4 3 * \binom 2 1 = 4 * 2 = 8 $$
So we have $15 - (1+8) = 9$ possibilities, which gives us the probability $\frac 9 {15} = 0.6 \Rightarrow $ probability of taking 2 red sweeties = $1 - 0.6 = 0.4$.