On an oriented Riemannian manifold $M$ one has the natural inner product on each $\Omega^n(M)$, defined by $\langle \alpha, \beta\rangle = \int_M \alpha\wedge *\beta $ where $*$ is the Hodge star. It is also natural to let $\Omega^*(M)=\bigoplus_{n=0}^{\dim M}\Omega^n(M)$; the direct sum of inner product space also becomes an inner product space, simply by adding the products. Nothing can stop you now from completing $\Omega^*(M)$ with respect to the inner product to get a Hilbert space; the elements of the resulting space are the forms with $L^2$ coefficients. Which, of course, raises the issue of the definition of operator $d$. One considers the smaller Hilbert space of forms with $H^1$ coefficients (Sobolev space) on which $d$ is defined, but takes values in the larger space of forms with $L^2$ coefficients. Now we can dualize and say that $d$ also maps $L^2$ forms into $H^{-1}$ forms, where $H^{-1}$ is the Sobolev space of negative order, defined as the dual of $H^1$. Note that $H^{1}\subset L^2\subset H^{-1}$, so we have a rigged Hilbert space.
A classical reference for the above is Chapter 7 of Multiple integrals in the calculus of variations by Morrey. If you don't have access to it, take a look, e.g., at this paper. These two references lean into analysis. A geometric point of view is presented in Chapter 6 of Warner's Foundations of differentiable manifolds and Lie groups. Warner works with the inner product on $\Omega^*(M)$ defined above, but avoids taking the completion as long as he can. By the time the Sobolev spaces appear, the computation is moved to a Euclidean space.
This said, I agree with @Qiaochu that you don't need an inner product. Completeness is essential, of course, but there are other options:
But if you don't want to choose a metric on $M$, then you'll have to carefully define an LCS (locally convex topological vector space) of smooth forms using the family of seminorms given by the integrals against all smooth vector fields. And then deal with completeness and integration issues. Looks like an unnecessary effort.