You can solve this problem using simple techniques from calculus. We want to show that
5^{n} > n + 4^{n} ~~~\mbox{ for }~~~ n \geq 2
First, I will write $n$ as $x$ to indicate that we are working with real numbers, not just natural ones.
$5^{x} > x + 4^{x} ~~~\mbox{ for }~~~ x \geq 2$
Next, we evaluate this inequality at $x=2$. This becomes
$ 25 = 5^{2} > 2 + 4^{2} = 18$
Which is certainly true. Now, we need only to show that the left-hand side grows more quickly than the right hand side, so that the this strict inequality is maintained as $x$ increases. This is equivalent to showing that the derivative of the left-hand side is larger than the derivative of the right-hand side for $x \geq 2$. Taking derivatives, we get
$5^{x}\log(5) > 1 + 4^{x}\log(4) ~~~\mbox{ for }~~~ x \geq 2$
Again, at $x=2$, this just becomes
$5^{2}\log(5) > 1 + 4^{2}\log(4) $
which is easy to verify. We could go through the work of showing that the left-hand derivative is larger than the right-hand one, but the $1$ on the right-hand side makes this a little tricky. So, we repeat our technique above. The left-hand derivative is larger than the right-hand derivative at $x=2$. If it grows faster than the right-hand derivative for $x \geq 2$, we will be done. Thus, we take derivatives again, to obtain
$5^{x}\log(5)\log(5) > 4^{x}\log(4)\log(4) ~~~\mbox{ for }~~~ x \geq 2$
Which is trivially true, because every factor on the left-hand side is larger than the corresponding factor on the right-hand side. Thus, the left-hand derivative grows faster than the right hand-derivative, and thus is greater than it for $x \geq 2$, which means that the left-hand side of our original equality, $5^{x}$, is greater than the right hand side, $x + 4^{x}$, for $x \geq 2$.
Noting that the natural numbers are contained in the real ones, we are done. QED
In general, the above technique is probably not what the question wants from you. For that, you should read the other answers. This just highlights a generally useful `brute-force' way of showing such inequalities.