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Given two random variables X = cos(θ) and Y = sin(θ), where θ is uniformly distributed over [0,π], they are not independent. How can I prove this non-independence rigorously?

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    $x^2+y^2=1$,thus they are not independent2012-10-19

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You can deduce the value of $Y$ from that of $X$, $y=\sqrt{1-x^2}$. Thus you have full knowledge of $y$ given $x$, whereas independence implies that knowing $x$ gives you no knowledge at all about $y$.

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    @Dilip: You're right; fixed.2012-10-19