By the Cosine Law, we have $c^2=a^2+b^2-2ab\cos(C).$ This can be rewritten as $\cos(C)=\frac{a^2+b^2-c^2}{2ab}.$
Put $a=2.3$, $b=4.6$, and $c=5.9$. We get $\cos(C)=-0.395051$. So far, we agree.
Pressing the $\cos^{-1}$ button, we get $C=113.27128$ (degrees). Doing it in radian mode, we get $C=1.9769568$ (radians). But probably you want the answer in degrees.
You do not explain why you think the answer is not correct. I noticed that in your first line you say that $b=4.9$, but in your calculation you write $4.6$, and indeed you used $4.6$. If $b$ was really supposed to be $4.9$, you should redo the calculation using $b=4.9$.
One other possibility is that you do not know how to find $C$, knowing its cosine and the fact that the angle is between $0$ and $180$. The notation is a little confusing. Note that $\cos^{-1}x$ does not mean $\frac{1}{\cos x}$.
In a comment, you mention that the issue is with "$-0.395051$", but do not explain why you see it an issue. I will guess that it is the fact that the number is negative. No problem! The cosine of any obtuse angle is negative. The reason we got a negative is that $c^2>a^2+b^2$. In that case, the angle $C$ will always be obtuse.