Looks to me like this was a homework problem given by a careless or lazy instructor, since there are no such other quadratic fields.
First task: verify that your extension is not normal. As you’ve seen, the complete set of roots of your irreducible equation is $\{\pm\sqrt{2+i},\pm\sqrt{2-i}\}$. I’ll call these $\pm\xi$ and $\pm\eta$. To see that $\eta$ is not in your field $F= {\mathbb{Q}}(i,\xi)$, you need only check that the ratio between $\xi^2$ and $\eta^2$ as elements of ${\mathbb{Q}}(i)$ is not a square. This ratio is $(2+i)^2/5$, not a square since $5$ isn’t.
Next step is easy, to describe carefully what the normal closure (over ${\mathbb{Q}}$) is, and it’s simply ${\mathbb{Q}}(i,\xi,\eta)$, which you’ve already observed contains $\sqrt5$.
Now for the Galois group. Let's call $a$ the automorphism that exchanges $\xi$ and $\eta$, and $b$ the one that leaves $\xi$ fixed, sends $\eta$ to $-\eta$. They’re both involutions (square to the identity), and $ab$, by which I mean $b$ first, then $a$, sends $\xi\mapsto\eta\mapsto-\xi\mapsto-\eta\mapsto\xi$, so is of period four. You’ve got the dihedral group of order eight. This has five subgroups of order two, only one of them being normal, and three subgroups of order four, all of them normal, being of index two. I won’t go through the details of enumerating the elements of each subgroup, rather I include a (crude) field diagram, in which you see that the only quartic field that has two quadratic subfields is the normal one, ${\mathbb{Q}}(i,\sqrt5)$. Of course you have to verify all this yourself.
