If the base is $2c$ and the height is $h$, then the roof framing cross sections are shown in blue below. Note that the triangles with sides $ach$ & $bch$ are congruent (mirror images, reflections about $h$), so really $a=b$ have the same length. (We only confuse things by using two variable names for them!) Furthermore, this length is the hypotenuse of a right triangle with horizontal and vertical legs $c$ & $h$, respectively, and we can use its trigonometry to find its complementary interior acute angles, which I will call $\alpha$ and $\beta$.

Now the angle $\beta$ opposite $h$, the roof's angle, has slope (or pitch) $\frac23$, from which we get $\beta$ using the arctangent (inverse tangent) function (with your calculator's angle mode set to degrees rather than radians): $ \tan\beta=\frac{h}{c}=\frac23\qquad\implies\qquad\beta =\tan^{-1}\frac23=0.588\text{ rad}=33.69^\circ $ and the angle you want (opposite $c$ inside each congruent triangle at the top) is $ \tan\alpha=\frac{c}{h}=\frac32\qquad\implies\qquad\alpha =\tan^{-1}\frac32=0.9828\text{ rad}=56.31^\circ. $ That is, you need to cut an acute angle $\alpha=90^\circ-\beta$ on each piece of wood, to get a total angle of $2\alpha$ at the top of the roof. As to the lengths, they are given by the famous Pythagorean formula: $ \eqalign{ a^2=b^2&=h^2+c^2\\&=2^2+3^2\\&=4+9\\&=13 \\\\ a=b &=\sqrt{13} \approx 3.60555\text{ ft} \\ &\approx 3\text{ ft }7.26661\text{ in} \\ &\approx 3\text{ ft }7\tfrac4{15}\text{ in} \\ &\approx 3\text{ ft }7\tfrac14\text{ in} \\ &\approx 109.9\text{ cm} } $ The alternate length unit and fraction are slightly more precise, but perhaps less convenient to work with.
Perhaps you should ask another question about how this roof pitch will look aesthetically and function, i.e. how it will reflect light and whether it will adequately absorb solar radiation (would you ever want to put a solar panel or passive heating unit there?) based on its orientation (map direction, for lighting source and relation to where people will be, for modeling sun shading and reflections) and your latitude and average yearly weather conditions.