I didn't notice the "countable family" part, sorry. Maybe this answer is still of some value.
I will assume $k=1$ here for convenience. The joint distribution function $F(t_2, \dotsc, t_n)$ for $T_2, \dotsc, T_n$ is the product of the individual distribution functions:
$ F(t_2, \dotsc, t_n) = \prod_{m=2}^nq_m e^{-q_mt_m}. $
The joint distribution for all variables is therefore
$ q_1e^{-q_1t_1}F(t_2, \dotsc, t_n). $
The requested probability is then expressed by the integral
$ \int_{\Omega}q_1e^{-q_1t_1}F(t_2, \dotsc, t_n) dt_1 \cdots dt_n $
where $\Omega$ is the set that matches the conditions for this probability:
$ \Omega = \{ (t_1, \dotsc, t_n) \mid t_1 \geq t \textrm{ and } t_m \geq t_1 \textrm{ for } m = 2, \dotsc, n \} $
Write the integral more explicitly in terms of the coordinates to get
$ \int_t^{\infty} \int_{t_1}^{\infty} \cdots \int_{t_1}^{\infty} q_1e^{-q_1t_1}F(t_2, \dotsc, t_n) dt_n \cdots dt_2 dt_1 = \\ \int_t^{\infty} q_1e^{-q_1t_1} \int_{t_1}^{\infty} \cdots \int_{t_1}^{\infty} F(t_2, \dotsc, t_n) dt_n \cdots dt_2 dt_1 = \\ \int_t^{\infty} q_1e^{-q_1t_1} \mathbb{P}(T_m \geq t_1 \textrm{ for } m=2, \dotsc, n) dt_1 $