So, let $F$ be a finite field. As you said, the cardinal $q$ of $F$ is a prime power $q = p^e$ and $F$ is isomorphic to $\mathbb F_q$. The prime subfield of $F$ (the subfield generated by 1) is then isomorphic to $\mathbb F_p$. With a slight abuse of notation, I will from now on identify $F$ with $\mathbb F_q$ and its prime subfield with $\mathbb F_p$, so I consider the inclusion $\mathbb F_p \subseteq \mathbb F_q$.
Theorem. $\mathbb F_p = \{ x \in \mathbb F_q \, | \, x^p = x\}.$
Proof.
First, $\mathbb F_p \subseteq \{ x \in \mathbb F_q \, | \, x^p = x\}$. Indeed, Fermat's little theorem says that $\forall a \in \mathbb Z, a^p \equiv a \, (\mathrm{mod}\, p)$. In more abstract terms, that means that $\forall x \in \mathbb F_p, x^p = x$, which is the inclusion I mentioned. (BTW, this finite field business gives a neat proof of Fermat's little theorem: Lagrange's theorem for the multiplicative group $\mathbb F_p^\times$ gives $\forall x \in \mathbb F_p \setminus \{0\}, x^{p-1} = 1$, and deducing Fermat's little theorem is now childplay.)
To prove the opposite inclusion, note that it is enough to prove that $\{ x \in \mathbb F_q \, | \, x^p = x\}$ cannot have more than $p$ elements (because what we just did already gives $p$ elements). But that is a particular case of a more general result: in a (commutative) field, a polynomial of degree $d$ cannot have more than $d$ roots. (By Euclidean division, $a$ is a root of $P$ iff $(X-a)$ divides $P$ so a polynomial having $d$ roots is a multiple of $(X-a_1)\cdots (X-a_d)$. If it is nonzero, that implies $\deg P \geq d$.)
So the theorem is proved. The arguments I gave are enough to prove that more generally, if $K \subseteq F$ is an extension of finite fields, $K = \{ x \in F \, | \, x^q = x\}$, where $q = |K|$.