We don't know what a well-ordering of the real numbers looks like. Not only because it is a non-constructive object (i.e. its existence is provable, but not describable in ZFC), but also because the length of this well-ordering is undecidable in ZFC.
Namely, suppose that the real numbers could be well-ordered. Take an ordering of minimal length. Is this an order of length $\omega_1$? $\omega_5$? $\omega_{\omega_{\omega_1}}$?
The axioms of ZFC are not sufficient to calculate the exact length of the well-ordering of the reals; and the axioms of ZF are not sufficient to prove the existence of such well-ordering (but I wrote about this enough in the linked posts).
As for the elements? Well, that is impossible to tell if the set is not canonically well-ordered, like the natural numbers. Consider the rationals, those are well-orderable (it is a countable set). What is the least rational in the well-ordering? What is its successor? We can't really tell. We can always choose a well-ordering that its first element is $0$ and the second is $42$; we can describe a few more elements; we can even describe longer pieces. However there is no canonical way to do that.
Similarly even if the real numbers are well-orderable we can't really point out a particular well-ordering because of that. We can always take a permutation of the real numbers to define a new well-ordering.
Either way, however, describing only a countable part of the real numbers is not enough to describe a well-ordering of them all because Cantor's theorem tells us the real numbers are uncountable.