Let $X$ and $Y$ be topological spaces. Let $\langle X,Y\rangle$ denote the homotopy classes of maps from $X$ and $Y$. The reduced suspension $\Sigma(-)$ has the adjoint $\Omega(-)$. In other words, we have $ \langle \Sigma X, Y \rangle\cong \langle X,\Omega Y\rangle $ for all $X$ and $Y$.
I am always confused with on which side I should put $\Sigma$. What is the easiest or intuitive way to think of this isomorphism? Are there a good way to memorize this this formula?