Let $X$ be a random variable with mean $\mu$ and standard deviation $\sigma>0$. Then the Chebyshev Inequality says that if $k>0$, then $P(|X-\mu| \ge k\sigma)\le \frac{1}{k^2}.$ In our case, $X$ is the length of a plank chosen at random from the company's production. Then $\mu=2.5$ and $\sigma=0.1$. We want to find $k$ such that $k\sigma=0.5$. Thus $k=\frac{0.5}{\sigma}=\frac{0.5}{0.1}=5$. We conclude that $P(|X-2.5| \ge 0.5) \le \frac{1}{5^2}.$
It follows that $P(|X-2.5| < 0.5) \ge 1-\frac{1}{5^2}.\tag{$\ast$}$ This is not quite what we want, since we want to find a number $p$ such that $P(|X-2.5| \le 0.5)\ge p$. One can argue that the probability that the difference is absolutely exactly $0.5$ is $0$, so that $(\ast)$ gives us the inequality we want. That gives a lower bound of $1-\frac{1}{5^2}=0.96$. There is a probability of at least $0.96$ that the plank does not differ by more than $0.5$ from the mean $2.5$.
Typically, the Chebyshev Inequality gives very conservative estimates. In our case, though Chebyshev says that $P(|X-2.5|\ge 0.5) \le \frac{1}{5^2}$, the actual probability is likely to be substantially smaller than $\frac{1}{5^2}$. Thus the lower bound of $0.96$ is likely conservative. Informally, more than $96\%$ of the production will be "within spec."