Here (I think) is a more elementary argument that doesn't use the Morse Lemma. Let me know what you guys think. For $\varepsilon < 1/2$, let $C_{\varepsilon} \subset \mathbb{R}^2$ denote the open cube of side length $2\varepsilon$ centered at $0$. Note that, for the smooth curves $\gamma_1, \gamma_2:(-\epsilon, \epsilon) \rightarrow \mathbb{R}^2$ given by $\gamma_1(t) = (t,t)$ and $\gamma_2(t) = (t,-t)$, we have $F(\gamma_1(t)) > 0$ and $F(\gamma_2(t)) < 0$ for $t \neq 0$. Let $R_1 = \{(x,y): -y 0\}$, $R_2 = \{(x,y): -y, $R_3 = \{(x,y): x0\}$, and $R_4 = \{(x,y): x (the open "quadrants" separated by the lines $y=x$ and $y=-x$). By the intermediate value theorem, $R_i \cap C_{\varepsilon} \cap F^{-1}(0) \neq \varnothing$ for each $i$. Now suppose for contradiction that $F^{-1}(0)$ is an embedded $1$-submanifold of $\mathbb{R}^2$, and let $(V, \varphi)$ be a coordinate chart for $F^{-1}(0)$ centered at $(0,0)$. By shrinking $V$ if necessary, we may assume that $V = C_{\epsilon} \cap F^{-1}(0)$ for some $\epsilon < 1/2$ and $\varphi(V)$ is an open interval. The open sets $R_1, R_2, R_3, R_4$ separate $V \smallsetminus \{(0,0)\}$ into at least four components, but $\varphi(V \smallsetminus \{(0,0)\}) = \varphi(V) \smallsetminus \{\varphi(0,0)\}$ has two components, a contradiction.