I'm assuming that you are taking f to be an arbitrary set map, $\mathcal{P}(X)$ to be the powerset of $X$ and $ker(f)$ to be the relation defined as follows:
If $f:X\to{}Y$ is a map of sets, then $ker(f)\subseteq{}X\times{}X$ consists of $(x,y)$ such that $f(x)=f(y)$. (For interested readers, this is in the literature -- see Jacobson's Basic Algebra II, the sections on set theory in the beginning.)
It is clear that $ker(f)$ is an equivalence relation, so that one may take the quotient space of equivalence classes $X/ker(f)$, which is a collection of subsets of $X$, i.e. an element of $\mathcal{P}(\mathcal{P}(X))$. So this is what your map $\psi$ does: it takes a map of sets $f:X\to{}Y$ to its collection of nonempty fibers (the collection of preimages of points in $Y$, $\{f^{-1}(\{y\})|y\in{}im(f)\}$).
Now, in your particular case, you are interested only in $f:\mathbb{R}\to{}\mathbb{N}$. Given what has been said above, the answer is that $\psi:\mathbb{N}^{\mathbb{R}}\to{}\mathcal{P}(\mathcal{P}(\mathbb{R}))$ is neither injective nor surjective.
Proof: (not injective) consider the constant map $n:\mathbb{R}\to{}\mathbb{N}$ defined by $n(x)=n$. Then $\psi(n)=\{\{\mathbb{R}\}\}$, and this is true for any $n\in{}\mathbb{N}$. (not surjective) Since we have a surjection of $im(f)\subseteq{}\mathbb{N}$ onto $\psi(f)$ given by taking $n\in{}im(f)$ to $f^{-1}(\{y\})$, it follows that $|\psi(f)|$ is at most countable. But the set $\{\{x\}|x\in\mathbb{R}\}$ is an uncountable element of $\mathcal{P}(\mathcal{P}(\mathbb{R}))$, so it cannot be in the image of $\psi$.