Since we are only interested in the angles, the actual lengths of the two sides do not matter, as long as we get their ratio right. So we can take the lengths of the adjacent sides to be $1$ and $3$, in whatever units you prefer. If you want the shorter of the two adjacent sides to be $20$ metres, then the other adjacent side will need to be $60$ metres. But we might as well work with the simpler numbers $1$ and $3$.
To compute the length of the third side, we use a generalization of the Pythagorean Theorem called the Cosine Law. Let the vertices of a triangle be $A$, $B$, and $C$, and let the sides opposite to these vertices be $a$, $b$, and $c$. For brevity, let the angle at $A$ be called $A$, the angle at $B$ be called $B$, and the angle at $C$ be called $C$. The Cosine Law says that $c^2=a^2+b^2-2ab\cos C.$ Take $C=60^\circ$, and $a=1$, $b=3$. Since $\cos(60^\circ)=1/2$, we get $c^2=1^2+3^2-2(1)(3)(1/2),$ so $c^2=7$ and therefore $c=\sqrt{7}$. We now know all the sides.
To find angles $A$ and $B$, we could use the Cosine Law again. We ilustrate the procedure by finding $\cos A$. By the Cosine Law, $a^2=b^2+c^2-2bc\cos A.$ But $a=1$, $b=3$, and by our previous work $c=\sqrt{7}$. It follows that $1=9+7-2(3)(\sqrt{7})\cos A,$ and therefore $\cos A= \frac{5}{2\sqrt{7}}.$ The angle in the interval from $0$ to $180^\circ$ whose cosine is $5/(2\sqrt{7})$ is not a "nice" angle. The calculator (we press the $\cos^{-1}$ button) says that this angle is about $19.1066$ degrees.
Another way to proceed, once we have found $c$, is to use the Sine Law $\frac{\sin A}{a}=\frac{\sin B}{b}=\frac{\sin C}{c}.$ From this we obtain that $\frac{\sin A}{1}=\frac{\sqrt{3}/2}{\sqrt{7}}.$ The calculator now says that $\sin A$ is approximately $0.3273268$, and then the calculator gives that $A$ is approximately $19.1066$ degrees. In the old days, the Cosine Law was not liked very much, and the Sine Law was preferred, because the Sine Law involves only multiplication and division, which can be done easily using tables or a slide rule. A Cosine Law calculation with ugly numbers is usually more tedious.
The third angle of the triangle (angle $B$) can be found in the same way. But it is easier to use the fact that the angles of a triangle add up to $180^\circ$. So angle $B$ is about $100.8934$ degrees.