$\mathbb{R}^n$ is still partially ordered by the product order, and it's still true that any automorphism must preserve the product order by the same argument. In fact the same argument as in the case of $\mathbb{R}$ shows that an automorphism of $\mathbb{R}^n$ is $\mathbb{R}$-linear.
(For those who aren't familiar with the argument, here's a quick sketch. First, any abelian group homomorphism of $\mathbb{Q}$-vector spaces is $\mathbb{Q}$-linear. Second, any ring homomorphism preserves the set of squares. Third, any $\mathbb{Q}$-linear map preserving squares is order-preserving, hence must in fact be $\mathbb{R}$-linear by approximating any real number from above and below by rationals.)
Actually much more is true. Let $X, Y$ be compact Hausdorff spaces and $C(X)$ the space of continuous functions $X \to \mathbb{R}$. Then it turns out that every ring homomorphism $C(Y) \to C(X)$ comes from a continuous map $X \to Y$ by precomposition. This is proven here and here. In particular setting $X = Y$ to be the discrete space with $n$ points it follows that $\text{Aut}(\mathbb{R}^n) \cong S_n$.
Here is a completely elementary way to finish the argument inspired by Chris Eagle's comment. Any automorphism permutes the idempotents, and these are precisely the elements whose entries are either $1$ or $0$. By linearity an automorphism is determined by what it does to the standard basis idempotents $e_i$, and it must send each $e_i$ to a distinct sum of some $e_j$'s. But this is also true of the inverse of the automorphism, so they compose to the identity if and only if each $e_i$ is sent to exactly one other $e_j$ (or else too many terms appear in the composite evaluated on $e_i$).