To my knowledge you cannot add vectors in polar / spherical coordinates by adding the components as you would in Cartesian coordinates. This is because even when the tails of the two vectors lie in the same point, the unit vectors in the $r$, $\theta$ and $\phi$ directions have different directions for the two different vectors. This means that the two vectors have e.g. two different $r$-directions and adding the two $r$ components to each other would be like adding apples and pears - something that is not allowed.
Here is a 2D example to prove my point:
Suppose you have two vectors that start in the origin of the coordinate system and respectively point to the two points A(1,0) and B(0,1) in the Cartesian coordinate system. Let's call these two vectors A and B.
In Cartesian coordinates we can add the two vectors by adding their components. Therefore, the sum of the two vectors are: C = A + B = [1 0] + [0 1] = [1 1]. You can draw these three vectors easily and confirm that they form a closed triangle.
Now let's convert the two points to polar coordinates and then do the same calculation. Points A and B in polar coordinates are: A(1,0) and B(1,$\frac{\pi}{2}$). If we now try to add the two vectors by adding their components, we get C = A + B = [1 0] + [1 $\frac{\pi}{2}$] = [2 $\frac{\pi}{2}$].
Converting this back to Cartesian coordinates yields [0 2] $\neq$ [1 1]. You can further confirm that the vector obtained from the polar coordinate addition does not form a closed triangle when drawn together with the two vectors that was added to obtain it.
It might be possible to derive a formula for adding vectors in polar / spherical coordinates, but I expect that this formula will in any case be a (quite complicated / ugly) form of a coordinate transformation.
So in conclusion, as far as I know, the simplest and safest solution is to convert the two vectors to Cartesian coordinates before adding them.