This is an example of achieving $a$ distinct sums for a stick of length $6a$. No specific integer occurs twice in any particular sum, or twice in two different sums, or more succinctly all the numbers involved in the sums are distinct. I think that is what the OP means in the statement of the "EDIT".
The triples are $T_k=[k,3a-2k+1,3a+k-1]$ for $1 \le k \le a.$ Each triple then has sum $6a$ as desired, and the numbers used are all distinct. The middle numbers are going down by 2 as $k$ runs through $\{1,2,...,a\}$ with the last one being $3a-2a-1=a+1$, just after the highest number $a$ of the first term in any triple, and the first middle number is the largest of the middle numbers namely $3a-2\cdot 1+1=3a-1,$ which is just before the lowest of the third elements of the triples, i.e. $3a+1-1=3a$. After that the third elements of the triples increase by 1 each step until reaching the highest third element of a triple, namely $3a+a-1=4a-1$ (So the last triple $T_a$ is $[a,a+1,4a-1]$).
I don't know if better can be done for a stick of length $6a$, but I haven't been able to prove that; it may be that some other sheme of getting different triples could give more than $a$ sums for the $6a$ long stick. What I tried to do was to have the middle numbers going down two each time, and make the block of them start right after the end of the first block going up one each time, and end just before the final block which again goes up one each time. I can't think of a denser way to pack the triples.
By the way in my opinion, given the restriction of no number used twice in any one triple or even anywhere on the list of triples obtained, the OP should specify whether his question is to find the maximal number of sums say $F(n)$ for a given stick length $n$, or on the other hand maybe the OP is interested in a formula of type $F(n,t)$ for the number of ways a stick of length $n$ can be cut into three parts in $t$ ways, no repeated numbers. The latter would be a lot harder, and even a provable formula for $F(n)$ would seem difficult, at least to me.
EDIT In this construction the "middle numbers" are spaced 2 apart. And in most cases more triples can be found in the unused numbers of the middle range. For example in the case $a=4$ with stick length $6a=24$, the $a=4$ triples formed using the construction are
$[1,11,12],\ [2,9,13],\ [3,7,14],\ [4,5,15]$
The unused numbers of the middle range make up another triple $[6,8,10],$ so that for stick length 24 one can find 5 triples.
For the case $a=10$ (stick length 60) besides the ten automatically constructed triples, the unused middle numbers are the nine even numbers from 12 through 28, and these can be put into the three triples $[12,20,28],\ [14,22,24],\ [16,18,26].$ So for stick length 60 the max number of triples is at least 13.