The fact that $u$ is divergence free does mean that $u$ is the curl of something, locally at least. The fact that we have, for some $v,$ that $u = \nabla \times v$ amounts to little more than the fact that mixed partial derivatives commute, and in general is called Poincare's Lemma. Furthermore, one can replace any such $v$ by $v + \nabla \cdot f$ for some function $f.$ As in the comments, there is therefore little reason to talk about an operator $\nabla^{-1},$ such a thing is not going to be well defined. If you want to give an exact reference and convince us that a responsible person wrote the material you are quoting, things might be different.